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WEEM-2019 is the ninth successive event of a series of International Workshops on Electrochemistry of Electroactive Materials (WEEM) started in Russia (Moscow, 1995) and followed by meetings in France (Dourdan, 1997), Poland (Poraj, 2000 and Szczyrk, 2009), Germany (Bad Herrenalb, 2003 and 2015), Russia (Repino, 2006), and Hungary (SzegedHódmezővásárhely, 2012). WEEMs are specifically designed conferences aiming at detailed analysis of the state-of-art and intensive discussions of key issues related to the research and applications of various electroactive systems. These systems include materials of quite different chemical natures, e.g. electron-conducting and redox polymers, mixed-valence transition-metal inorganic solids, solid ion conductors, lithium/sodium/potassium-cation intercalation systems as well as organic/polymeric-inorganic composites. Progress in the understanding of the complex mechanisms of their functioning and diverse applications requires bringing together leading scientists in various areas of research and providing them with the opportunity to combine presentations of original results with the possibility for extensive exchange of opinions. In-depth analysis of unresolved problems and identification of newly emerging issues is expected to occur so that it will result in further developments of the area as well as in the formation of competitive international teams able to face new scientific challenges.