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TITANIUM (+4) COORDINATION COMPOUNDS WITH 8- HYDROXYQUINOLINE DERIVATIVES AS CATALYSTS FOR HOMO- AND CO-POLYMERIZATION OF ETHYLENE AND 1- HEXENEдоклад на конференции
- Авторы: Kolosov N.A., Tuskaev V.A., Gagieva S.Ch
- Международная Конференция : IX International conference of young scientists on chemistry “Mendeleev - 2015”, St.Petersburg, April 7-10, 2015
- Даты проведения конференции: 7-10 апреля 2015
- Дата доклада: 8 апреля 2015
- Тип доклада: Стендовый
- Докладчик: Kolosov N.A.
- Место проведения: St.Petersburg, Russia
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Аннотация доклада:
Coordination compounds of titanium (+4) with 8-hydroxyquinoline derivatives have been synthesized. Composition and properties of the obtained complexes have been evaluated by NMR, IR spectroscopy, X-ray diffraction,and elemental analysis.Titanium complexes were evaluated in their capacity as catalysts of the ethylene polymerization and ethylene/1-hexene copolymerization in the presence of cocatalysts - diethylaluminum chloride/dibutylmagnesium or methylaluminoxane. All obtained coordination compounds demonstrated high catalytic activities in homo- and co-polymerization reactions.
- Добавил в систему: Колосов Николай Александрович