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On the interaction of tri-n-butylmethylphosphonium dimethylphosphate with elemental sulfurдоклад на конференции
- Авторы: Кривобородов Е.Г., Занин А.А., Межуев Я.О., Тарасова Н.П.
- Международная Конференция : 8th IUPAC International Conference on Green Chemistry
- Даты проведения конференции: 9-14 сентября 2018
- Дата доклада: 13 сентября 2018
- Тип доклада: Стендовый
- Докладчик: не указан
- Место проведения: Бангкок, Thailand
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Аннотация доклада:
The interaction of tri-n-butylmethylphosphonium dimethylphosphate with elemental sulfur was described. The reaction products are isolated and characterized with 1H, 13C, 31P and 17O NMR spectroscopy. It is shown that dimethyl phosphateanion is active in the reaction, and the addition of sulfur atoms occurs through the oxygen atom of dimethyl phosphate-anion. It is found that a mixture of products, which differ in the number of sulfur atoms in the chain, is formed The assumptions were made about the mechanism of interaction of sulfur with tri-n-butylmethylphosphonium dimethylphosphate.
- Добавил в систему: Кривобородов Ефрем Георгиевич