ИСТИНА

Herein synthesis of series of new fluorine containing tricyclononenes using [2σ+2σ+2π] cycloaddition of quadricyclane with fluorine containing alkenes is described. According to the experiment the range of reactivity for fluorine containing alkenes was found. The obtained cycloadducts were then subjected to ring-opening metathesis polymerization on Ru-based catalytic systems. Investigation of gas separation properties of new materials with improved selectivity towards different pairs of gases is executed.