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Organic materials are highly perspective for lasing and sensing applications in different photonic elements due to their high and tunable refractive index and luminescent yield and ease of manipulation with shape and composition. Here we report on the fabrication by a self-assembly technique and nonlinear-optical characterization of binol- and perylene- based resonant microstructures supporting excitation of whis- pering gallery modes (WGM) with Q-factor up to 700 in photoluminescence (PL) spectrum and waveguiding of nonlinear signal with low loss.