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The paper addresses a novel interface-capturing approach for two-phase flows governed by the five-equation diffuse interface model. To suppress the numerical diffusion of the interface, we introduce a primitive sub-cell reconstruction based on volume fractions in neighbouring cells. This reconstruction gives rise to a Riemann problem (CRP) with an additional contact discontinuity, so-called composite Riemann problem, which is stated on mixed cell faces. The CRP solution is used to calculate the numerical flux across cell faces of mixed cells with taking into account the interface reconstructed patterns. A hybrid HLL-HLLC method is incorporated to approximate the solution of the CRP. The proposed approach is shown to effectively reduce the interface numerical diffusion without introducing spurious oscillations. Its performance and robustness is examined by 1D and 2D numerical tests.