ИСТИНА

Using different approaches, a series of carbon and boron substituted nido-carborane derivatives with a side substituent containing additional N-donor group was prepared. The synthesized derivatives were used as ligands in the complexation reactions with various phosphine complexes of nickel(II) and palladium(II). As a result, the nido-carborane based half-sandwich complexes with different types of coordination of ligand with metal center were obtained.