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Alkynes are important building blocks in organic chemistry and are easily converted into many other compounds. In recent decades, the chemistry of acetylene has received intense attention from chemists due tothe use of alkynes as building blocks or versatile intermediates for the synthesis of a wide variety of chemicals. This development in alkyne chemistry has been driven mainly by the development of new synthetic methodologies based on transition metal catalysis, a field in which gold and palladium has always been atthe first place. Currently, photocatalytic methods for the functionalization of alkynes are among emerging trends of research. Recent methods for the catalytic functionalization of alkynes will be presented and discussed based on our recent results.