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The mechanism of formation and 1D growth of aluminum oxyhydroxide nanofibrils during the oxidation of the surface of liquid aluminum alloys remains an unresolved fundamental physicochemical problem. Nevertheless, the synthesis methods for oxide 1D and 3D nanomaterials on the surface of liquid aluminum alloys are being successfully developed in the temperature range from 25 to 670 °C. Highly porous monolithic 3D nanomaterials with the functional properties promising for application as IR-THz range optical elements, as waveguides, antenna arrays and nonlinear media: photonic crystals and hyperbolic metamaterials have been synthesized.