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An analysis was carried out of the change in the energy of the system upon the convergence of various intermediates, the formation of which is expected in the catalytic and non-catalytic stages of the oxidative polymerization of aniline. It has been shown that the auto-acceleration of aniline polymerization can be associated with the coordination of the monomer by the resulting polymer. The proximity of aniline and its oxidation products leads to a decrease in the energy of the system.