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Synthesis and characterization of new energetic 1,2,4,5-tetrazines obtained from bis-3,6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine with 5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one in presence of bases was described. Was shown possibility of synthesis energetic salts with amines in example of reaction of 4,4'-(1,2,4,5-tetrazine-3,6-diyl)bis(5-nitro-2,4-dihydro-3H-1,2,4-triazol-3-one) with triaminoguanidinium chloride. Estimate of thermal stability new energetic compounds was conducted by differential scanning calorimetry.