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Homogeneous Pd(0)-catalyzed amination reactions can be successfully applied to the synthesis of N-aryl and N-heteroaryl substituted linear polyamines, nitrogen-containing macrocycles, macropolycycles and biologically active derivatives of adamantane-containing amines. The application of much cheaper copper catalysis also allows (hetero)arylation of amines and polyamines. The selectivity of the copper-mediated reactions dramatically depends on the nature of (poly)amines and (hetore)aryl halides and on the composition of the catalytic system.
№ | Имя | Описание | Имя файла | Размер | Добавлен |
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1. | Краткий текст | EuropaCat_2017_Abel_abstract.pdf | 467,8 КБ | 9 декабря 2018 [Antonabel507] |