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3D Frameworks with Variable Magnetic and Electrical Features from Sintered Cobalt-Modified Carbon Nanotubesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 10 августа 2018 г.
- Авторы: Savilov Serguei V., Chernyak Sergei A., Paslova Maria S., Ivanov Anton S., Egorova Tolganay B., Maslakov Konstantin I., Chernavskii Petr A., Lu Li, Lunin Valery V.
- Журнал: ACS applied materials & interfaces
- Том: 10
- Номер: 24
- Год издания: 2018
- Издательство: American Chemical Society
- Местоположение издательства: United States
- Первая страница: 20983
- Последняя страница: 20994
- DOI: 10.1021/acsami.8b04367
- Аннотация: 3D frameworks of carbon nanotubes (CNTs) uniformly decorated by cobalt oxide or carbon-encapsulated cobalt nanoparticles were obtained by spark plasma sintering for the first time. The influence of the sintering temperature (TS) and Co content on the morphology, structure, and electrical and magnetic properties of the obtained materials was investigated by Raman spectroscopy, electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, and in situ magnetometry. It was shown that application of the SPS technique allowed simultaneous compaction of the material, formation of CNT framework, and Co oxide reduction. The appearance of the carbon shell around 4–10 nm Co particles was observed at TS > 600 °C. At higher TS, the Co particle size increased (up to 300 nm at 1400 °C), whereas the carbon shell ordered and thickened. The formation of large-size few-layers graphene sheets was observed at TS = 1400 °C. Electrical conductivity of the composites was found to be higher than that of sintered pristine CNTs and varied in the range of 500–12 500 Sm/m. Magnetic experiments demonstrated soft magnetization of the samples and the coercivity of 200–300 Oe. Thus, the obtained CNT-based material is simultaneously compact, formable, electroconductive, and ferromagnetic. Its properties can be tuned by variation of the sintering parameters. Synthesized cobalt-modified carbon 3D structures are promising for the application in magnetic separation, catalysis, fuel cells, and electromagnetic shielding.
- Добавил в систему: Черняк Сергей Александрович