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Overcoming the inertness of iridium(III) in a facile single‐crystal to single‐crystal reaction of iodine vapor with cyclometalated chloride monomerстатья
Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus- Авторы: Bezzubov Stanislav I., Kalle Paulina, Bilyalova Alfiya A., Tatarin Sergei V., Dolzhenko Vladimir D.
- Журнал: Chemistry - A European Journal
- Год издания: 2018
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- DOI: 10.1002/chem.201801963
- Аннотация: Iridium(III) is often considered to be one of the most inert octahedral metal ions. Herein we present a phenanthroimidazole‐based bis‐cyclometalated iridium(III) chloride undergoing a facile chloro ligand exchange with iodine in a gas‐solid reaction under ambient conditions. Monitoring the progress of the reaction by X‐ray diffraction analysis reveals the crystal‐packing‐induced exceptional stereoselectivity of this topochemical transformation. The results provide excellent opportunities to modulate the geometry and kinetic properties of cyclometalated iridium(III) complexes that may be very promising in catalysis and design of anticancer agents.
- Добавил в систему: Беззубов Станислав Игоревич