Spontaneous Association of the Terbium Cyclopentadienyl Complexes under Controlled Hydrolysisстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 10 августа 2018 г.
Аннотация:Controlled hydrolysis of the terbium cyclopentadienyl complexes results in the formation of the
heteroligand tetranuclear terbium complex [{Tb(η5-C5H5)}3{Tb(THF)3}(μ3-Cl)(μ2-Cl)6(μ4-O)] (I), the recrystallization of which from tetrahydrofuran (THF) gives solvatomorph I · 0.5THF (Ia). According to the X-ray structure analysis data (CIF files CCDC 1569329 (I) and 1569330 (Ia)), the complexes are tetrahedral with the μ4-bridging O2– anion at the center of the tetrahedron. The cyclopentadienyl ligand in complex I is shown to act as an “antenna” providing luminescence of the complex.