Titanium(IV) Complexes Based on Tridentate N,N,O Ligands – Synthesis, Structure, and Thermal Decompositionстатья
Статья опубликована в высокорейтинговом журнале
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Дата последнего поиска статьи во внешних источниках: 20 января 2016 г.
Аннотация:New tridentate N,N,O-type ligands MeN(CH2CH2NHTs)(CH2CR2OH) [Ts = tosyl ; R = H, 6, (N,N,OH)H2; R = Ph, 7 (N,N,OPh)H2] were prepared. The corresponding diisopropoxide complexes (N,N,OH)Ti(OiPr)2 (8) and [N,N,OPh]Ti(OiPr)2 (9) were obtained through the reactions of 6 and 7 with Ti(OiPr)4. These complexes are thermally unstable and transform into the bisligated complexes [N,N,OH]2Ti (10) and [N,N,OPh]Ti(OiPr)2O (11). The molecular structures of 10 and 11 were investigated by X-ray diffraction analysis. The synthesis of 11 from 9 as a thermal decomposition process was studied.