COMPUTER-ASSISTED INVESTIGATION OF POSSIBLE REARRANGEMENTS OF (CH)N (N=4,6,8,10) ANNULENESстатья
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Аннотация:Application of the computer program for the rationalization and prediction of possible rearrangements in annulenes with the common formula (CH)n (n = 4-10) is considered. Processes of [2 + 2]-, [2 + 2 + 2]-, [4 + 2]-cycloaddition and [4]-, [6]- electrocyclic reactions in the families of annulenes are discussed. A list of all possible reactions proceeding as [1,3]-, [1,5]-, [3,3]-sigmatropic shifts in cyclopolyene structures is presented. The whole set of unknown annulene reactions is reproduced. A wide set of prospective rearrangements is predicted, including several interesting examples of the degenerate Cope rearrangement.