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Multimodal Metal Cation Sensing with Bis(macrocyclic) Dyeстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Elena Tulyakova, Stephanie Delbaere, Yuri Fedorov, Gedaminas Jonusauskas, Anna Moiseeva, and Olga Fedorova*[
- Журнал: Chem. Eur. J. 10752 10752 – 10762
- Том: 17
- Год издания: 2011
- Первая страница: 10752
- Последняя страница: 10762
- DOI: 10.1002/chem.201100998
- Аннотация: The synthesis, electrochemical, optical, and cation sensing properties of a bis(macrocyclic) dye 1, in which the benzo-15-crown-5 and phenylazathia- 15-crown-5 subunits are linked through a styryl pyridinium moiety, are reported. In this new ditopic receptor, the benzo-15-crown-5 macrocycle acts as a highly selective binding site for alkaline earth metal cations (MgII and BaII), whereas the phenylazathia- 15-crown-5 displays a strong binding affinity towards soft heavy-metal cations (HgII and AgI). The pronounced changes of the absorption and fluorescence spectra of this bichromophoric dye observed upon different metal cation addition make the dye suitable for dual-wavelength analysis and offer an enticing potential for multitasking sensors.
- Добавил в систему: Моисеева Анна Анисимовна