Kinetic models of the cyclohexene hydromethoxycarbonylation catalyzed by the Pd(OAc)2 /trans -2,3-bis(diphenylphosphinomethyl)norbornane/p -toluensulfonic acidстатья
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Аннотация:Operating over the entire length from the region of initial rates to deep conversions of
cyclohexene, hydromethoxycarbonylation kinetic models have been obtained in the temperature range of 358–378 K. At 378 K, a conclusion on a higher stability of the diphosphine complex [HPd(TBDPN)(CH3OH)]OTs compared to [HPd(CO)2OTs]under hydromethoxycarbonylation conditions has been made based on the comparison of the kinetic model constant values.