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Kinetic models of the cyclohexene hydromethoxycarbonylation catalyzed by the Pd(OAc)2 /trans -2,3-bis(diphenylphosphinomethyl)norbornane/p -toluensulfonic acidстатья
- Авторы: Sevostyanova Nadezhda, Batashev Sergey, Nifant'ev Ilya, Vinogradov Alexander, Tavtorkin Alexander
- Журнал: International Journal of Chemical Kinetics
- Год издания: 2019
- Издательство: John Wiley & Sons Inc.
- Местоположение издательства: United States
- DOI: 10.1002/kin.21250
- Аннотация: Operating over the entire length from the region of initial rates to deep conversions of cyclohexene, hydromethoxycarbonylation kinetic models have been obtained in the temperature range of 358–378 K. At 378 K, a conclusion on a higher stability of the diphosphine complex [HPd(TBDPN)(CH3OH)]OTs compared to [HPd(CO)2OTs]under hydromethoxycarbonylation conditions has been made based on the comparison of the kinetic model constant values.
- Добавил в систему: Нифантьев Илья Эдуардович