Structure of the electrode-solution interface in the presence of organic solutions adsorbed in two different positionsстатья
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Дата последнего поиска статьи во внешних источниках: 28 мая 2015 г.
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Авторы:
Damaskin B.B.,
Frumkin A.N.,
Dyatkina S.L.
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Журнал:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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Том:
16
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Номер:
10
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Год издания:
1968
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Первая страница:
2088
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Последняя страница:
2094
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DOI:
10.1007/BF00913288
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Аннотация:
1. Quantitative functions permitting calculation of the dependence of the adsorption, interfacial tension, and differential capacitance upon the electrode potential, as well as the dependence of the point of zero charge upon the adsorption in systems where the organic substance can be adsorbed on the electrode in two different positions, were obtained on the basis of a model of three parallel condensers. 2. A comparison of the results of the calculation with the experimental data on the adsorption of ortho- and para-phenylendiamines on mercury shows that the model of three parallel condensers is a good semiquantitative basis for describing systems of this type. © 1968 Consultants Bureau.
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Добавил в систему:
Дамаскин Борис Борисович