Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matricesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 13 мая 2020 г.
Аннотация:Upon the photolysis (l = 546 nm) of X-ray irradiated
cyclopentene oxide/Freon solutions at 77 K, irreversible
proton abstraction in the ring-open form of the cyclopentene
oxide radical cation occurs, affecting the bridgehead carbon.
This affords unstable 6-oxabicyclo[3.1.0]hexan-1-yl radicals,
which undergo rearrangement to form ring-open terminal
C-centered alkyl radicals detected as final products.