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Spectroelectrochemistry of intercalated single-walled carbon nanotubesстатья
- Авторы: Eliseev A.A., Verbitskiy N.I., Verbitskiy I.I., Lukashin A.V., Kumskov A.S., Kiselev N.A.
- Журнал: Physica Status Solidi (B): Basic Research
- Том: 253
- Номер: 6
- Год издания: 2016
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- DOI: 10.1002/pssb.201600029
- Аннотация: The method of Raman spectroelectrochemical detection of charge transfer in doped single-walled carbon nanotubes is suggested and tested for the determination of the electronic structure of “1D crystal@SWNT” composites. Spectroelectrochemical study of CuCl@SWNT composites in resonant Raman conditions revealed a significant Kohn anomaly shift of ca. −0.7 eV corresponding to redox doping of metallic 1.4 nm nanotubes and related to Fermi level downshift. The obtained results are consistent with data available from XPS and optical spectroscopy.
- Добавил в систему: Елисеев Андрей Анатольевич