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Conversion of cellulose with the use of catalysts based on hypercrosslinked polystyreneстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Дата последнего поиска статьи во внешних источниках: 12 сентября 2019 г.
- Авторы: Matveeva V.G., Manaenkov O.V., Filatova A.E., Kislitza O.V., Doluda V.YU, Rebrov E.V., Sulman1 E.M., Sidorov A.I., Torozova A.S.
- Сборник: WSEAS TRANSACTIONS on ENVIRONMENT and DEVELOPMENT
- Том: 12
- Год издания: 2016
- Первая страница: 133
- Последняя страница: 140
- DOI: 10.1063/1.4968069
- Аннотация: The study presents the results of cellulose hydrolytic hydrogenation process in subcritical water in the presence of Ni, Fe, Pt, Pd, Au and Ru-containing catalysts based on hypercrosslinked polystyrene (HPS) MN-270 and its functionalized analogues: NH2-HPS (MN-100) and SO3H-HPS (MN-500). Nonfunctionalized HPS was shown to be the optimal carrier for these catalysts, and Ru-containing catalysts are the most active in the process of cellulose conversion into polyols. In this case the total yield of sorbitol and mannitol was 50% on the average at 85% cellulose conversion. On the basis of the experimental and computed data the pathway of hydrolytic hydrogenation of cellulose was suggested.
- Добавил в систему: Торозова Александра Сергеевна