New representative of Bi95+-containing phases: synthesis and crystal structure of the NbIV-containing Bi10Nb3Cl18 compoundстатья
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Дата последнего поиска статьи во внешних источниках: 20 мая 2018 г.
Аннотация:The Bi10Nb3Cl18 compound was prepared using the high-temperature ampoule method, and its crystal structure was determined by single-crystal X-ray diffraction. This phase contains the Bi95+ cluster polycations and Bi+ cations surrounded by the NbCl62– complex anions. The latter contain the paramagnetic central NbIV ions, as evidenced by magnetic measurements.