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The competition kinetics of radical-chain additionстатья
Информация о цитировании статьи получена из
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Дата последнего поиска статьи во внешних источниках: 20 января 2016 г.
- Автор: Silaev M.M.
- Журнал: Russian Journal of Physical Chemistry A
- Том: 73
- Номер: 7
- Год издания: 1999
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 1050
- Последняя страница: 1054
- Аннотация: A scheme of reactions involving radicals of three types, one of which inhibits the chain process, is suggested and used to derive kinetic equations with one to three parameters that should be determined experimentally. The equations describe a nonmonotonic (with a maximum) dependence of the rate of the addition of a free radical to a double bond with the formation of a 1:1 adduct on the concentration of the unsaturated compound; they apply to unbranched chain processes in liquid homogeneous binary mixtures comprising saturated (hydrocarbon, alcohol, etc.) and unsaturated (olefin, formaldehyde, or molecular oxygen) components.
- Добавил в систему: Силаев Михаил Михайлович
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | A scheme of reactions involving radicals of three types, one of which inhibits the chain process, is suggested and used to derive kinetic equations with one to three parameters that should be determined experi- mentally. The equations describe a nonmonotonic (with a maximum) dependence of the rate of the addition of a free radical to a double bond with the formation of a 1 : 1 adduct on the concentration of the unsaturated com- pound; they apply to unbranched chain processes in liquid homogeneous binary mixtures comprising saturated (hydrocarbon, alcohol, etc.) and unsaturated (olefin, formaldehyde, or molecular oxygen) components. | M.M._Silaev_Russ._J._Phys._Chem._A_1999_737_1050-54.pdf | 172,4 КБ | 11 января 2016 [SilaevMM] |