Thermally stable hydrogen compounds obtained under high pressure on the basis of carbon nanotubes and nanofibers

Bashkin, I.O.; Antonov, V.E.; Bazhenov, A.V.; Bdikin, I.K.; Borisenko, D.N.; Krinichnaya, E.P.; Moravsky, A.P.; Harkunov, A.I.; Shul’ga, Y.M.; Ossipyan, Y.A.; Ponyatovsky, E.G.

Авторы: Bashkin I.O., Antonov V.E., Bazhenov A.V., Bdikin I.K., Borisenko D.N., Krinichnaya E.P., Moravsky A.P., Harkunov A.I., Shul’ga Yu M., Ossipyan Yu A., Ponyatovsky E.G.
Журнал: JETP Letters
Том: 79
Номер: 5
Год издания: 2004
Издательство: Maik Nauka/Interperiodica Publishing
Местоположение издательства: Russian Federation
Первая страница: 226
Последняя страница: 230
DOI: 10.1134/1.1753421
Аннотация: Compounds containing 6.3-6.5 wt % H and thermally stable in vacuum up to 500degreesC were obtained by annealing graphite nanofibers and single-walled carbon nanotubes in hydrogen atmosphere under a pressure of 9 GPa at temperatures up to 450degreesC. A change in the X-ray diffraction patterns indicates that the crystal lattice of graphite nanofibers swells upon hydrogenation and that the structure is recovered after the removal of hydrogen. It was established by IR spectroscopy that hydrogenation enhances light transmission by nanomaterials in the energy range studied (400-5000 cm(-1)) and results in the appearance of absorption bands at 2860-2920 cm(-1) that are characteristic of the C-H stretching vibrations. The removal of about 40% of hydrogen absorbed under pressure fully suppresses the C-H vibrational peaks. The experimental results are evidence of two hydrogen states in the materials at room temperature; a noticeable portion of hydrogen forms C-H bonds, but the most of the hydrogen is situated between the graphene layers or inside the nanotubes.
Добавил в систему: Антонов Владимир Евгеньевич

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Thermally stable hydrogen compounds obtained under high pressure on the basis of carbon nanotubes and nanofibersстатья