The Key Role of Active Sites in the Development of Selective Metal Oxide Sensor Materials

Marikutsa, A.; Rumyantseva, M.; Konstantinova, E.A.; Gaskov, A.

Авторы: Marikutsa Artem, Rumyantseva Marina, Konstantinova Elizaveta A., Gaskov Alexander
Журнал: Sensors
Том: 21
Год издания: 2021
Издательство: MDPI
Местоположение издательства: Basel, Switzerland
Первая страница: 1
Последняя страница: 43
Номер статьи: 2554
DOI: 10.3390/s21072554
Аннотация: Development of sensor materials based on metal oxide semiconductors (MOS) for selectivegas sensors is challenging for the tasks of air quality monitoring, early fire detection, gas leaks search, breath analysis, etc. An extensive range of sensor materials has been elaborated, but no consistent guidelines can be found for choosing a material composition targeting the selective detection of specific gases. Fundamental relations between material composition and sensing behavior have not been unambiguously established. In the present review, we summarize our recent works on the research of active sites and gas sensing behavior of n‐type semiconductor metal oxides with different composition (simple oxides ZnO, In2O3, SnO2, WO3; mixed‐metal oxides BaSnO3, Bi2WO6), andfunctionalized by catalytic noble metals (Ru, Pd, Au). The materials were variously characterized.The composition, metal‐oxygen bonding, microstructure, active sites, sensing behavior, and interaction routes with gases (CO, NH3, SO2, VOC, NO2) were examined. The key role of active sites in determining the selectivity of sensor materials is substantiated. It was shown that the metal‐oxygen bond energy of the MOS correlates with the surface acidity and the concentration of surface oxygen species and oxygen vacancies, which control the adsorption and redox conversion of analyte gas molecules. The effects of cations in mixed‐metal oxides on the sensitivity and selectivity of BaSnO3 and Bi2WO6 to SO2 and VOCs, respectively, are rationalized. The determining role of catalytic noble metals in oxidation of reducing analyte gases and the impact of acid sites of MOS to gas adsorption are demonstrated.
Добавил в систему: Марикуца Артем Валерьевич

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