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Aging of Thin-Film Composite Membranes Based on Crosslinked PTMSP/PEI Loaded with Highly Porous Carbon Nanoparticles of Infrared Pyrolyzed Polyacrylonitrileстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 4 июня 2021 г.
- Авторы: Bakhtin D., Bazhenov S., Polevaya V., Grushevenko E., Makaev S., Karpacheva G., Volkov V., Volkov A.
- Журнал: Membranes
- Том: 10
- Номер: 12
- Год издания: 2020
- Издательство: MDPI Publishing
- Местоположение издательства: Basel, Switzerland, Switzerland
- Первая страница: 419
- Последняя страница: 434
- DOI: 10.3390/membranes10120419
- Аннотация: The mitigation of the physical aging of thin-film composite (TFC) poly[1-trimethylsilyl-1-propyne] (PTMSP) membranes was studied via the simultaneous application of a polymer-selective layer crosslinking and mixed-matrix membrane approach. For the first time, a recently developed highly porous activated carbon material (infrared (IR) pyrolyzed poly[acrylonitrile] (PAN) or IR-PAN-a) was investigated as an additive to a PTMSP-selective layer for the reduction of aging in TFC membranes. The total electric energy spent on the IR irradiation treatment of IR-PAN-a particles was twice lower than conventional heating. The flat-sheet porous microfiltration membrane MFFK-1 was used as a support, and the crosslinked PTMSP/PEI loaded with a porous filler was applied as a selective layer (0.8–1.8 µm thick) to the TFC membranes. The initial IR-PAN-a sample was additionally milled to obtain a milled IR-PAN-aM sample with a monomodal particle size distribution of 500–800 nm. It was shown that IR-PAN-a, as a filler material with a high surface area and pore volume (2450 m2/g and 1.06 cm3/g, respectively) and a well-developed sponge-like structure, leads to the increase of the N2, O2, and CO2 permeance of PTMSP-based hybrid membrane material and the decrease of the aging of PTMSP. The simultaneous effect of crosslinking and the addition of a highly porous filler essentially improved the aging behavior of PTMSP-based TFC membranes. The monomodal and narrow particle size distribution of highly porous activated IR-pyrolyzed PAN is a key factor for the production of TFC membranes with reduced aging. The highest stability was achieved by the addition of a milled IR-PAN-aM sample (10 wt%). TFC membrane permeance was 6300 GPU (30% of initial permeance) after 11,000 h of aging at ambient laboratory conditions.
- Добавил в систему: Грушевенко Евгения Александровна