Diamidoamine Aluminum Complexes: Synthesis, Structure, L–Lactide and ϵ-Caprolactone Polymerizationстатья
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Дата последнего поиска статьи во внешних источниках: 24 ноября 2021 г.
Аннотация:A series of methyl and chlorido aluminum complexes decorated with diamidoamine ligands with different number of carbon atoms in the alkyl chains were prepared via methane elimination, salt methatesis route, transmetallation strategy or chlorination. They were investigated by various methods including 19F, 27Al NMR spectroscopy and showed to be active catalysts of ring-opening polymerization of ε-Cl and L-La.