Mercury(II) chloride in the synthesis of nido-carborane derivatives with B-N, B-O and B-S bondsстатьяИсследовательская статьяЭлектронная публикация
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 8 апреля 2022 г.
Аннотация:The use of mercury(II) chloride for the synthesis of nidocarborane derivatives with B–O, B–N, and B–S bonds is considered. The use of HgCl2 makes it possible to selectively obtain symmetrically substituted nido-carborane derivatives in high yields. The derivatives obtained can enter into various reactions of modification of the organic substituent or be used for the synthesis of metallacarboranes. The structure of 6,6'-diphenyl-8,8'-di(dimethylsulfide) derivative of iron(II) bis(dicarbollide) was determined by single crystal X-ray diffraction study.