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The Concentration of C(sp3) Atoms and Properties of an Activated Carbon with over 3000 m2/g BET Surface Areaстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 26 января 2022 г.
- Авторы: Shulga Yury M., Kabachkov Eugene N., Korepanov Vitaly I., Khodos Igor I., Kovalev Dmitry Y., Melezhik Alexandr V., Tkachev Aleksei G., Gutsev Gennady L.
- Журнал: Nanomaterials
- Том: 11
- Номер: 5
- Год издания: 2021
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 1324
- DOI: 10.3390/nano11051324
- Аннотация: The alkaline activation of a carbonized graphene oxide/dextrin mixture yielded a carbon-based nanoscale material (AC-TR) with a unique highly porous structure. The BET-estimated specific surface area of the material is 3167 m2/g, which is higher than the specific surface area of a graphene layer. The material has a density of 0.34 g/cm3 and electrical resistivity of 0.25 Ω·cm and its properties were studied using the elemental analysis, transmission electron microscopy (TEM), electron diffraction (ED), X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray induced Auger electron spectroscopy (XAES), and electron energy loss spectroscopy (EELS) in the plasmon excitation range. From these data, we derive an integral understanding of the structure of this material. The concentration of sp3 carbon atoms was found to be relatively low with an absolute value that depends on the measurement method. It was shown that there is no graphite-like (002) peak in the electron and X-ray diffraction pattern. The characteristic size of a sp2-domain in the basal plane estimated from the Raman spectra was 7 nm. It was also found that plasmon peaks in the EELS spectrum of AC-TR are downshifted compared to those of graphite
- Добавил в систему: Кабачков Евгений Николаевич