CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridines

Kuliukhina, D.S.; Averin, A.D.; Panchenko, S.P.; Abel, A.S.; Savelyev, E.N.; Orlinson, B.S.; Novakov, I.A.; Correia, C.R.; Beletskaya, I.P.

Информация о цитировании статьи получена из Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 20 апреля 2022 г.

Авторы: Kuliukhina D.S., Averin A.D., Panchenko S.P., Abel A.S., Savelyev E.N., Orlinson B.S., Novakov I.A., Correia C.R.D, Beletskaya I.P.
Журнал: Russian Journal of Organic Chemistry
Том: 58
Номер: 2
Год издания: 2022
Издательство: Maik Nauka/Interperiodica Publishing
Местоположение издательства: Russian Federation
Первая страница: 167
Последняя страница: 174
DOI: 10.1134/S1070428022020014
Аннотация: The N-heteroarylation of n-octylamine and adamantane-containing amines with 2-iodopyridine and 2-bromopyridine and its fluorinated derivatives under the catalysis of CuI and copper nanoparticles in DMSO in the presence of various ligands was studied. 2-Isobutyrylcyclohexanone was found to be the most efficient ligand in the reactions catalyzed by CuI. In the reactions catalyzed by copper nanoparticles, 2-isobutyrylcyclohexanone or l-proline turned to be most active. The yields of the reactions catalyzed by copper nanoparticles were better than or equal to those in the CuI-catalyzed processes. The possibility of nanocatalyst recycling was studied, and its reuse in 6 cycles without loss of activity was demonstrated.
Добавил в систему: Абель Антон Сергеевич

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CuI and Copper Nanoparticles in the Catalytic Amination of 2-Halopyridinesстатья

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