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Synthesis, crystal structure, thermal properties of copper(II) acrylate complex with 4$\prime$-phenyl-2,2$\prime$:6$\prime$,2$\prime$$\prime$-terpyridine and its use in nanomaterials scienceстатья
- Авторы: Uflyand Igor E., Tkachev Valerii V., Zhinzhilo Vladimir A., Drogan Ekaterina G., Burlakova Victoria E., Sokolov Mikhail E., Panyushkin Victor T., Baimuratova Rosa K., Dzhardimalieva Gulzhian I.
- Журнал: Journal of Molecular Structure
- Том: 1250
- Год издания: 2022
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 131909
- DOI: 10.1016/j.molstruc.2021.131909
- Аннотация: The reaction between copper(II) acrylate and 4′-phenyl-2,2′:6′,2″-terpyridine resulted in a new metal-containing monomer 1, which was characterized by elemental analysis, FTIR spectroscopy, and single-crystal X-ray diffraction analysis. Complex 1 crystallizes in triclinic form with space group P-1. The chelate node of complex 1 is close to an ideal tetragonal pyramidal structure and includes three nitrogen atoms of the terpyridine ligand and two oxygen atoms of acrylate fragments. Medium-strong hydrogen bond interactions lead to infinite 1D chains. The kinetic and thermodynamic parameters of the thermolysis process of complex 1 were studied. As a result of thermolysis process, nanomaterials of the [email protected] core-shell type were obtained. The resulting nanomaterials are effective antiwear and antifriction additives for lubricating oils.
- Добавил в систему: Баймуратова Роза Курмангалиевна