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Chiral macrocyclic compounds comprising endocyclic fragment of 2,2’-diamino-1,1’-binaphthaleneтезисы доклада
- Авторы: Malysheva A.S., Grigorova O.K., Averin A.D., Beletskaya I.P.
- Сборник: XXI МЕНДЕЛЕЕВСКИЙ СЪЕЗД ПО ОБЩЕЙ И ПРИКЛАДНОЙ ХИМИИ. Сборник тезисов в 6 томах
- Том: 5
- Тезисы
- Год издания: 2019
- Место издания: Без издательства Санкт-Петербург
- Первая страница: 194
- Последняя страница: 194
- Аннотация: Pd(0)-catalyzed amination was successfully applied to the synthesis of the macrocyclic compounds comprising endocyclic chiral fragment of (S)-2,2’-diamino-1,1’-binaphthalene (BINAM). Macrocycles differ by the nature of the aromatic spacer (phenylene, naphthalene), the length of the polyoxadiamine chain, the presence of the exocyclic fluorophore groups (dansyl, coumarin, quinoline) and additional chiral substituents with nitrogen and oxygen atoms increasing the number of coordination sites of the molecules. Thus synthesized macrocycles were investigated as enantioselective fluorescent detectors of six pairs of chiral amino alcohols, the possibility of the use of selective quenching or enhancement of the emission by one of enantiomers for detection was demonstrated.
- Добавил в систему: Малышева Анна Сергеевна