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Аннотация:In the title structure, [Ti2(C16H16N2O2)2O2]2CHCl3, the Ti atom is coordinated in a distorted octahedral geometry by the O,N,N0,O0 donor set of the salalen ligand and by two 2-oxide O atoms, which bridge two Ti(salalen) fragments into a centrosymmetric dimeric unit. In the central Ti2(2-O)2 fragment, the metal.oxygen distances are significantly different [1.7962 (19) and 1.9292 (19) A]. In the crystal, the chloroform molecule is anchored via an N.H Cl and a bifurcated C.H (O,O) hydrogen bond. Slipped pi-pi stacking [shortest C_C distance = 3.585 (4) A and C-H_pi interactions contribute to the coherence of the structure.