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Titelbild: Angew. Chem. 23/2002статья
- Авторы: Abbati Gian Luca, Caneschi Andrea, Cornia Andrea, Fabretti Antonio C., Pozdniakova Yulia A., Shchegolikhina Olga I.
- Журнал: Angewandte Chemie
- Том: 114
- Номер: 23
- Год издания: 2002
- Первая страница: 4533
- Последняя страница: 4533
- DOI: 10.1002/1521-3757(20021202)114:23<4533::aid-ange4533>3.0.co;2-h
- Аннотация: The cover picture shows a magnetic cluster, which was rationally designed by following a two-step synthetic approach (color code: light blue = Cu, orange = Si, gray and white = C, dark blue = N, red = O). The compound, which features ten copper(II) ions in three different coordination environments (trigonal-bipyramidal, square-pyramidal and square-planar), was obtained in crystalline form by self-assembly of four monodentate [Cu(tmpa)(CN)]+ units (tmpa=tris(2-pyridylmethyl)amine) around a preformed hexacopper(II)-siloxanolate cage, [Cu6{(PhSiO2)6}2]. Further details on the synthesis, structure, and magnetic properties are reported
- Добавил в систему: Щеголихина Ольга Ивановна