Synthesis of new non-proteinogenic amino acids with methylenebisphosphonic acids moieties via a convenient catalytic silicon-assisted routeтезисы доклада
Аннотация:The new non-proteinogenic amino acids with methylenebisphosphonic acids moieties are synthesized for the first time via unique reaction of tris(trimethylsilyl) phosphite and various N-formyl amino acids at the presence of effective catalyst – trimethylsilyl triflate under mild conditions