Аннотация:In the present work novel derivates of tris(3-aminopropyl)amine and tris(2-aminoethyl)amine eachbearing three aryl- or heteroaryl substituents were synthesized using catalyst-free and Pd(0)-catalyzedamination reactions. The regularities of the catalytic reactions depending on the nature of the starting compounds were studied, the possibility of the Pd(0)-catalyzed macrocyclization reactions involving bromophenyl and dansyl substituted tetraamines was investigated. The targer compounds possess bromophenyl, dansyl, 3- and 6-quinolinyl substituents thus providing perspective receptors for metal cations with fluorophore groups.