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The Basic Theorem of Temperature-Dependent Processesстатья
- Авторы: Sapunov Valentin N., Saveljev Eugene A., Voronov Mikhail S., Valtiner Markus, Linert Wolfgang
- Журнал: Thermo
- Том: 1
- Номер: 1
- Год издания: 2021
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 45
- Последняя страница: 60
- DOI: 10.3390/thermo1010004
- Аннотация: The basic theorem of isokinetic relationships is formulated as “if there exists a linearcorrelation “structureproperties” at two temperatures, the point of their intersection will be a common point for the same correlation at other temperatures, until the Arrhenius law is violated”.The theorem is valid in various regions of thermally activated processes, in which only one parameter changes. A detailed examination of the consequences of this theorem showed that it is easy to formulate a number of empirical regularities known as the “kinetic compensation effect”, the wellknown formula of the Meyer–Neldel rule, or the so-called concept of “multi-excitation entropy”. In a series of similar processes, we examined the effect of different variable parameters of the process onthe free energy of activation, and we discuss possible applications.
- Добавил в систему: Савельев Евгений Алексеевич