Nitrosonium hexachlorostannate: synthesis, crystal structure, and nitrosating activity in the reactions with arylcyclopropanesстатья
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Аннотация:Nitrosonium hexachlorostannate (NO)(2)[SnCl(6)] was synthesized by the reaction of NOCl and SnCl(4) in CH(2)Cl(2). According to the single-crystal X-ray diffraction analysis data, the structure of (NO)(2)[SnCl(6)] consists of cations NO(+) and octahedral anions [SnCl(6)](2-) arranged as ions in antifluorite. Isoxazolines were synthesized by the reactions of (NO)(2)[SnCl(6)] with arylcyclopropanes containing donor substituents in the aromatic ring.