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Three-coordinate silver(I) ions and tridentate ligands as complementary tectons in coordination polymer construction: a new example of semiregular 4.8(2) netsстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Vatsadze S.Z., Vatsadze I.A., Manaenkova M.A., Zyk N.V., Churakov A.V., Antipin M.Yu, Howard J.A.K, Lang H.
- Журнал: Russian Chemical Bulletin
- Том: 56
- Номер: 9
- Год издания: 2007
- Издательство: Springer Nature
- Местоположение издательства: Switzerland
- Первая страница: 1775
- Последняя страница: 1781
- DOI: 10.1007/s11172-007-0276-9
- Аннотация: The structures of the reaction products of silver nitrate with monoheterotopic tridentate ligands derived from N-alkyl-3,5-bis(3-pyridylmethylene)piperidin-4-one were studied. The aliphatic nitrogen atoms are involved in the coordination, all three nitrogen atoms of the ligands being coordinated to three different silver atoms. In turn, each silver atom is coordinated by two nitrogen atoms of the pyridine ring and one nitrogen atom of the piperidine ring of different ligands. The crystal structures of the complexes are different. Infinite ladder-like chains consisting of 16-membered metallamacrocycles as monomeric building blocks are present in the structure of the N-methyl derivative, whereas two-dimensional 4.8(2) nets consisting of 16-and 40-membered metallamacrocycles are observed in the crystal structure of the N-benzyl analog.
- Добавил в систему: Зык Николай Васильевич