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Reactions of Cr, Mo, W, and Mn carbonyls with 3,6-di-tert-butyi-o-quinone under the action of elastic wave pulsesстатья
- Авторы: Aleksandrov A.L., Prokof'ev A.L., Soiodovnikov S.P., Bubnov N.N., Aleksandrov L.A., Lebedev Ya S.
- Журнал: Russian Chemical Bulletin
- Том: 45
- Номер: 11
- Год издания: 1996
- Издательство: Springer Nature
- Местоположение издательства: Switzerland
- Первая страница: 2780
- Последняя страница: 2784
- Аннотация: Solid-state reactions of Cr, Mo, W, and Mn carbonyls with 3,6-di-tert-butyl-o-benzoquinone (Q) proceeding in molded powder-like mixtures (carbonyI--Q) treated with pulses of elastic waves were studied. The products of the reactions of Q with Cr(CO)6, Mo(CO)6, and W(CO) 6 are paramagnetic semiquinone complexes of Cr, Mo, and W. The formation of two semiquinone complexes with one or two manganese atoms was detected in the reaction of Mn2(CO)I0 with Q.
- Добавил в систему: Александров Алексей Иванович