New systems for classical nitrosohalogenation of alkenes - 2. Generation of nitrosyl chloride in AgNO2-SOCl2 and AgNO3-SOCl2 systemsстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:Study of the reactions of compounds of the norbornene series demonstrated that the AgNO2-SOCl2 and AgNO3-SOCl2 systems serve as nitrosochlorinating agents under the conditions of electrophilic addition. X-ray diffraction study showed that dimerization of cis-cxo-2-chloro-3-nitrosobicyclo[2.2.1]heptane occurs heterostereospecifically. The origin of the active principle of the reagents is discussed.