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Effect of Carbon on Formation of Mixed Solid Solutions during Mechanochemical Synthesis of Ni–Al–Mo–C Mixtures and Ordering of Solutions during Heating/статья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Дата последнего поиска статьи во внешних источниках: 28 мая 2015 г.
- Авторы: Portnoi V.K., Leonov A.V., Streletskii A.N., Logacheva A.I.
- Журнал: The Physics of Metals and Metallography
- Том: 115
- Номер: 3
- Год издания: 2014
- Первая страница: 277
- Последняя страница: 285
- DOI: 10.1134/S0031918X14030089
- Аннотация: Solid solutions Ni(Al, Mo, C) are formed via milling the Ni2.8Al1Mo0.2 and Ni3Al0.8Mo0.2 and graphitecontaining Ni2.8Al1Mo0.2C(0.25, 0.5) and Ni3Al0.8Mo0.2C(0.25, 0.5) mixtures. In this case, some amount of Mo remains beyond the solid solution. Graphite added to a starting mixture decreases the Mo solubility and favors the amorphization of solid solutions. The complete amorphization was found for the mixture with the 5 at % C and 5 at % Mo, which was added instead of Ni. The heating of mechanically synthesized (MS)powder alloys leads to the ordering of carbonfree and carboncontaining solid solutions with the formation of the L12 and E21 structure, respectively. During the ordering of the Ni(Al, Mo, C) solid solutions, Mo and carbon precipitate in the form of the molybdenum carbide (Mo2C) second phase. The hardness of the MS threephase Ni–Al–Mo–C solid solutions subjected to hot isostatic pressing is determined by the mass fraction of the formed Mo2C carbide. It is shown that the carbon content in the multicomponent antiperovskite can be estimated by analyzing the ratio of integral intensities of superlattice reflections I(100)/I(110).
- Добавил в систему: Портной Валерий Кимович