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Impact of Ge Doping on Structural and Magnetic Ordering in RMnxGa3 and R4Mn1–xGa12Gey (R = Tb, Dy; x ≤ 0.25, y ≈ 1.0–3.3)статья Исследовательская статья
Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus- Авторы: Kulchu Aleksandr, Khalaniya Roman A., Mironov Andrei V., Khrykina Olga N., Verchenko Valeriy Yu, Stern Raivo, Shevelkov Andrei V.
- Журнал: Inorganic Chemistry
- Том: 62
- Номер: 33
- Год издания: 2023
- Издательство: American Chemical Society
- Местоположение издательства: United States
- Первая страница: 13348
- Последняя страница: 13361
- DOI: 10.1021/acs.inorgchem.3c01671
- Аннотация: Single crystals of RMnxGa3 and their new quaternary derivatives R4Mn1–xGa12–yGey (R = Tb, Dy, x ≤ 0.25, y ≈ 1.0–3.3) were grown from a Ga flux. The compounds are derivatives of cubic RGa3 phases, with Mn atoms filling the Ga6 voids. RMnxGa3 formally adopts a cubic ABO3 perovskite structure, in which the presence of Mn atoms results in a shift of the neighboring Ga atoms from their ideal position. A partial substitution of Ga by Ge leads to a higher Mn content, resulting in structural ordering of the latter and the formation of the superstructure phases R4Mn1–xGa12–yGey, which can be formally described in the Y4PdGa12 structure type. The presence of Mn vacancies, which was observed for R = Tb, and Ga/Ge mixing lead to a noticeable deviation from the idealized structure. The compounds contain two magnetic sublattices: the R sublattice, which orders antiferromagnetically near 20 K, and the Mn sublattice, which orders ferromagnetically at TC = 125–225 K with the Ge doping resulting in higher TC. The two sublattices are not independent, as the Mn sublattice induces partial ferromagnetic ordering of the rare earth atoms below TC, at least for the Ge-doped phases. Near TN, both magnetic susceptibility and heat capacity reveal complex behavior, indicating changes in magnetic structures below TN.
- Добавил в систему: Халания Роман Андреевич