Аннотация:A complex [Mn(5-F-sal2323)]2[ReCl6] was synthesized and its crystal structure and magnetic properties were studied in comparison with complexes [Mn(5-Cl-sal2323)]2[ReCl6] and [Mn(5-Br-sal2323)]2[ReCl6] showing spin crossover and field-induced single-ion magnetism.