Potentialities of thermal lens spectrometry in studying peculiarities of reactions at the trace levelстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:It was shown that thermal lensing can be used for studying peculiarities of the reactions at the nanogram reactant concentrations. Examples of determining molar absorptivities, dissociation constants of acids, cumulative and stepwise stability constants of complexes, characteristic rate constants, solubility constants, and other parameters using the data of thermal-lens experiments are presented. In a number of cases, taking into account reaction conditions at the nanogram level improves the performance characteristics of the determination.