Furfural Hydrogenation in the Presence of Ru and Pd Catalysts Immobilized on Hybrid Materials Based on Mesoporous Phenol–Formaldehyde Polymers and Silica

Авторы: Boronoev M.P., Shakirov I.I., Roldugina E.A., Kardasheva Yu S., Kardashev S.V.
Журнал: Russian Journal of Applied Chemistry
Том: 96
Номер: 11
Год издания: 2023
Издательство: Maik Nauka/Interperiodica Publishing
Местоположение издательства: Russian Federation
Первая страница: 944
Последняя страница: 952
DOI: 10.1134/s1070427223110036
Аннотация: Catalysts based on Ru and Pd nanoparticles on mesoporous hybrid supports consisting of mesoporous phenol–formaldehyde polymers and silica were synthesized. The catalysts were tested in furfural hydrogenation at 150–250°С and hydrogen pressure of 3 MPa. In furfural hydrogenation in the presence of the Pd catalyst, the yield of tetrahydrofurfuryl alcohol was 99% when performing the reaction in ethanol, whereas the Ru catalyst showed high selectivity with respect to cyclopentanone (80%) in furfural hydrogenation in water. The hybrid catalysts exhibit higher activity than the polymer analogs.
Добавил в систему: Бороноев Максим Павлович

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