Аннотация:Bulk SiO2-PbF2 oxyfluoride glasses co-doped with dispersed luminescent Ag nanoclusters and Tm3+ ions have been prepared by conventional melt-quenching method. Luminescence from 400 to 900 nm has been excited in this glass by UV light from 340 to 400 nm. The prepared glass has potential for application as a low cost glass phosphor in Hg-free white light generation in UV-driven devices, flexible monitors and as down-shifting layers for enhanced solar cells. Co-doping with Tm3+, which has an absorption band H-3(6)-> D-1(2), affects the tint of the total Ag-Tm3+ white emission band of this glass by changing the excitation wavelength to about 365 nm, which is almost the same wavelength as that of a commercial LED.